4.2.3

Electromotive force and potential difference

Cambridge IGCSE Physics (0625)  · Unit 4: Electricity and magnetism  · 14 flashcards

Electromotive force and potential difference is topic 4.2.3 in the Cambridge IGCSE Physics (0625) syllabus , positioned in Unit 4 — Electricity and magnetism , alongside Simple phenomena of magnetism, Electric charge and Electric current.  In one line: Electromotive force (e.m.f.) is the electrical work done by a source in moving a unit charge around a complete circuit. This work done is measured in Joules per Coulomb (J/C) or Volts (V).

This topic is examined in Paper 1 (multiple-choice) and Papers 3/4 (theory), plus Paper 5 or Paper 6 (practical / alternative to practical).

The deck below contains 14 flashcards — 4 definitions — covering the precise wording mark schemes reward.  Use the 4 definition cards to lock down command-word answers (define, state), then move on to the concept and application cards to handle explain, describe and compare questions.

Key definition

Electromotive force (e.m.f.)

Electromotive force (e.m.f.) is the electrical work done by a source in moving a unit charge around a complete circuit. This work done is measured in Joules per Coulomb (J/C) or Volts (V).

What the Cambridge 0625 syllabus says

Official 2026-2028 spec

These are the exact learning objectives Cambridge sets for this topic. Match the command word (Describe, Explain, State, etc.) in your answer to score full marks.

  1. Define Define electromotive force (e.m.f.) as the electrical work done by a source in moving a unit charge around a complete circuit
  2. Know Know that e.m.f. is measured in volts (V)
  3. Define Define potential difference (p.d.) as the work done by a unit charge passing through a component
  4. Know Know that the p.d. between two points is measured in volts (V)
  5. Describe Describe the use of voltmeters (analogue and digital) with different ranges
  6. Recall Recall and use the equation for e.m.f. Supplement
  7. Recall Recall and use the equation for p.d. Supplement
Definition Flip

Define electromotive force (e.m.f.).

Answer Flip

Electromotive force (e.m.f.) is the electrical work done by a source in moving a unit charge around a complete circuit. This work done is measured in Joules per Coulomb (J/C) or Volts (V).

Key Concept Flip

A battery transfers 12 Joules of energy to move 4 Coulombs of charge around a complete circuit. What is the electromotive force (e.m.f.) of the battery?

Answer Flip

e.m.f. = Work Done / Charge

e.m.f. = 12 J / 4 C

e.m.f. = 3 V

The electromotive force of the battery is 3 Volts. It represents the energy provided by the battery per unit charge passing through it.

Definition Flip

What unit is electromotive force (e.m.f.) measured in?

Answer Flip

Electromotive force (e.m.f.) is measured in volts (V).

Volts (V) are the SI unit for electrical potential difference, including e.m.f.

Key Concept Flip

A student measures the electromotive force (e.m.f.) of a battery. They record the value as 1.5. What is the unit missing from this measurement?

Answer Flip

The unit missing is volts (V).

Therefore, the correct measurement is 1.5 V. E.m.f is always measured in volts.

Definition Flip

Define potential difference.

Answer Flip

Potential difference is the work done per unit charge when charge flows between two points in a circuit. It is measured in Volts (V). This means 1 Volt is equal to 1 Joule per Coulomb (1 V = 1 J/C).

Key Concept Flip

A lightbulb has a potential difference of 6.0 V across it. Explain what this means, in terms of energy transfer and charge.

Answer Flip

A potential difference of 6.0V across the lightbulb means that for every 1 Coulomb of charge that passes through the bulb, 6.0 Joules of electrical energy is transferred into light and heat energy. The charge loses 6.0 J of energy as it moves through the bulb.

Definition Flip

What unit is used to measure potential difference?

Answer Flip

The unit used to measure potential difference is the volt (V).

Explanation: Potential difference, often referred to as voltage, quantifies the electrical potential energy difference between two points in a circuit. It is the 'push' that drives current.

Key Concept Flip

A battery is labelled as '3.0 V'. What does this label tell you about the battery?

Answer Flip

The label tells you that the potential difference (p.d.) across the terminals of the battery is 3.0 volts.

Explanation: This means the battery provides 3.0 Joules of electrical energy per Coulomb of charge that passes through it.

Key Concept Flip

Describe how you would use a voltmeter to measure the potential difference across a resistor in a circuit. Include details about the connections required.

Answer Flip

1. Select an appropriate range on the voltmeter. If the expected potential difference is unknown, start with the highest range and decrease until a reading is obtained without exceeding the scale.
2. Connect the voltmeter *in parallel* with the resistor. This means connecting one terminal of the voltmeter to each end of the resistor.
3. Ensure the positive terminal of the voltmeter is connected to the point in the circuit with the higher potential (usually the side connected to the positive terminal of the power supply).
4. Read the potential difference from the voltmeter's scale or digital display. The voltmeter displays the potential difference.

Key Concept Flip

You have an analogue voltmeter with ranges of 3V, 15V, and 30V. You need to measure the potential difference across a component in a circuit. You estimate the potential difference to be approximately 12V. Which range should you select and why?

Answer Flip

You should select the 15V range.

Reasoning: The 3V range is too low as the reading (12V) would exceed the scale and potentially damage the meter. The 30V range could be used, but it would result in a less precise reading as the needle would deflect less, making it more difficult to read accurately. Selecting 15V gives an appropriate reading on the scale.

Key Concept Flip

A battery with an internal resistance of 0.5 ohms delivers a current of 2.0 A to a circuit. If the terminal potential difference across the battery is 5.0 V, calculate the electromotive force (e.m.f.) of the battery.

Answer Flip

Formula: e.m.f. = V + Ir

e.m.f. = 5.0 V + (2.0 A * 0.5 Ω)

e.m.f. = 5.0 V + 1.0 V

e.m.f. = 6.0 V

Explanation: The e.m.f. is the total energy supplied per unit charge, which is the sum of the terminal potential difference (V) and the potential drop across the internal resistance (Ir).

Key Concept Flip

Explain why the terminal potential difference of a battery is always less than its electromotive force (e.m.f.) when the battery is supplying current to a circuit.

Answer Flip

When a battery supplies current, some energy is dissipated as heat due to the internal resistance of the battery. This energy loss results in a voltage drop (Ir) within the battery itself. Therefore, the terminal potential difference (V), which is the voltage measured across the battery's terminals, is equal to the e.m.f. minus the voltage drop due to the internal resistance (V = e.m.f. - Ir). Since Ir is always positive when a current is flowing, the terminal potential difference is always less than the e.m.f.

Key Concept Flip

A 6.0 V battery transfers 1200 J of energy to a circuit. Calculate the charge that flows through the circuit.

Answer Flip

Formula: V = W / Q, where V = potential difference, W = energy, and Q = charge.
Rearranging: Q = W / V
Calculation: Q = 1200 J / 6.0 V = 200 C
Answer: The charge that flows through the circuit is 200 Coulombs (C).

Key Concept Flip

Explain, in terms of energy transfer, what is meant by a potential difference of 9.0 V across a component.

Answer Flip

A potential difference of 9.0 V across a component means that 9.0 Joules (J) of energy are transferred per Coulomb (C) of charge that passes through the component. The charge loses 9 J of electrical energy to the component, which is then converted to other forms of energy.

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4.2.2 Electric current 4.2.4 Resistance

Key Questions: Electromotive force and potential difference

Define electromotive force (e.m.f.).

Electromotive force (e.m.f.) is the electrical work done by a source in moving a unit charge around a complete circuit. This work done is measured in Joules per Coulomb (J/C) or Volts (V).

What unit is electromotive force (e.m.f.) measured in?

Electromotive force (e.m.f.) is measured in volts (V).

Volts (V) are the SI unit for electrical potential difference, including e.m.f.

Define potential difference.

Potential difference is the work done per unit charge when charge flows between two points in a circuit. It is measured in Volts (V). This means 1 Volt is equal to 1 Joule per Coulomb (1 V = 1 J/C).

What unit is used to measure potential difference?

The unit used to measure potential difference is the volt (V).

Explanation: Potential difference, often referred to as voltage, quantifies the electrical potential energy difference between two points in a circuit. It is the 'push' that drives current.

More topics in Unit 4 — Electricity and magnetism

Electromotive force and potential difference sits alongside these Physics decks in the same syllabus unit. Each uses the same spaced-repetition system, so progress in one informs the next.

Key terms covered in this Electromotive force and potential difference deck

Every term below is defined in the flashcards above. Use the list as a quick recall test before your exam — if you can't define one of these in your own words, flip back to that card.

Electromotive force (e.m.f.)
What unit is electromotive force (e.m.f.) measured in
Potential difference
What unit is used to measure potential difference

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