Reactivity series
Cambridge IGCSE Chemistry (0620) · Unit 9: Metals · 17 flashcards
Reactivity series is topic 9.2 in the Cambridge IGCSE Chemistry (0620) syllabus , positioned in Unit 9 — Metals , alongside Properties of metals, Extraction of metals and Uses of metals. In one line: Group 1 metals have fixed oxidation states. They consistently form +1 ions due to easily losing their one outer electron.
This topic is examined in Paper 1 (multiple-choice) and Papers 3/4 (theory), plus Paper 5 or Paper 6 (practical / alternative to practical). Past papers from 2022 to 2025 confirm this is a high-yield topic: Cambridge has set undefined questions worth 501 marks here (about 7.9% of all Chemistry marks across those years).
The deck below contains 17 flashcards — 2 definitions, 13 key concepts and 2 identification cards — covering the precise wording mark schemes reward. Use the 2 definition cards to lock down command-word answers (define, state), then move on to the concept and application cards to handle explain, describe and compare questions.
The oxidation states of Group 1 metals
Group 1 metals have fixed oxidation states. They consistently form +1 ions due to easily losing their one outer electron.
What the Cambridge 0620 syllabus says
Official 2026-2028 specThese are the exact learning objectives Cambridge sets for this topic. Match the command word (Describe, Explain, State, etc.) in your answer to score full marks.
- Describe Describe the uses of metals in terms of their physical properties, including: (a) aluminium in the manufacture of aircraft because of its low density (b) aluminium in the manufacture of overhead electrical cables because of its low density and good electrical conductivity (c) aluminium in food containers because of its resistance to corrosion (d) copper in electrical wiring because of its good electrical conductivity and ductility
Why is aluminium used in aircraft manufacture?
Aluminium is used in aircraft due to its low density. This reduces the overall weight of the aircraft, improving fuel efficiency and performance.
Why is aluminium used in overhead electrical cables?
Aluminium is suitable for overhead cables because it possesses both low density and good electrical conductivity. Low density minimizes the load on support structures, while good conductivity ensures efficient power transmission.
Explain why aluminium is used in food containers.
Aluminium is used in food containers due to its resistance to corrosion. This prevents the aluminium from reacting with the food, preserving its quality and safety.
Why is copper used in electrical wiring?
Copper is used in electrical wiring because of its good electrical conductivity and ductility. High conductivity allows for efficient electron flow, and its ductility allows it to be drawn into wires easily.
Do Group 1 metals show catalytic behavior?
No, Group 1 metals do not exhibit catalytic behavior. Transition metals are more commonly used as catalysts.
What are the oxidation states of Group 1 metals?
Group 1 metals have fixed oxidation states. They consistently form +1 ions due to easily losing their one outer electron.
Describe TWO observations you could make when potassium reacts with water.
Possible observations include: the potassium moves/floats on the water's surface; it dissolves/disappears as it reacts; bubbles/effervescence/fizzing occurs; a lilac flame is produced; the potassium may explode; the potassium melts/forms a spherical shape.
Write the balanced chemical equation for the reaction of potassium with water, including state symbols.
2K(s) + 2H₂O(l) → 2KOH(aq) + H₂(g). This equation shows that potassium reacts with water to produce potassium hydroxide and hydrogen gas.
How do the melting points of transition elements compare to those of Group 1 elements?
Transition elements generally have higher melting points compared to Group 1 elements. This is due to stronger metallic bonding.
How do the densities of transition elements compare to Group 1 elements?
Transition elements generally have higher densities than Group 1 elements. This relates to the size and arrangement of their atoms.
If chlorine is added to potassium bromide solution, what colour change is observed?
The solution changes from colourless to orange/brown. This is because bromine is displaced.
In the reaction between chlorine and potassium bromide, which element is reduced?
In the reaction between chlorine and potassium bromide, bromine is displaced. Chlorine gains electrons and is reduced.
State the reactivity series from most reactive to least reactive, including carbon and hydrogen.
Potassium > Sodium > Calcium > Magnesium > Aluminium > Carbon > Zinc > Iron > Hydrogen > Copper > Silver > Gold
Carbon and hydrogen are included as reference points: metals above carbon can be extracted by electrolysis only, while metals below carbon can be extracted by reduction with carbon.
What is a displacement reaction? Give an example.
A displacement reaction occurs when a more reactive metal takes the place of a less reactive metal in a compound.
Describe the reactions of potassium, sodium and calcium with cold water.
Potassium: reacts very vigorously, producing hydrogen which ignites with a lilac flame. Potassium moves rapidly on the water surface and may explode.
Sodium: reacts vigorously, producing hydrogen. Sodium melts into a ball and moves on the water surface. No flame usually seen.
Calcium: reacts slowly, sinking and producing a steady stream of bubbles (hydrogen). The solution turns milky due to slightly soluble calcium hydroxide.
For Group I: 2K + 2H₂O → 2KOH + H₂ (similar for Na).
For calcium: Ca + 2H₂O → Ca(OH)₂ + H₂
How can you deduce the order of reactivity from experimental results?
Compare how vigorously metals react with the same reagent (e.g., dilute acid or water):
• More reactive metals react faster, produce gas more quickly, or release more heat
• In displacement reactions, a more reactive metal will displace a less reactive one
• If metal A displaces metal B from solution, A is more reactive than B
Explain why aluminium appears unreactive despite being high in the reactivity series.
Aluminium quickly forms a thin, strong layer of aluminium oxide (Al₂O₃) on its surface when exposed to air. This oxide layer is very resistant to corrosion and prevents further reaction. The aluminium underneath is actually very reactive, but the protective oxide coating makes it appear unreactive. This is why aluminium is used for drinks cans and aircraft despite being above carbon in the reactivity series.
Key Questions: Reactivity series
What are the oxidation states of Group 1 metals?
Group 1 metals have fixed oxidation states. They consistently form +1 ions due to easily losing their one outer electron.
State the reactivity series from most reactive to least reactive, including carbon and hydrogen.
Potassium > Sodium > Calcium > Magnesium > Aluminium > Carbon > Zinc > Iron > Hydrogen > Copper > Silver > Gold
Carbon and hydrogen are included as reference points: metals above carbon can be extracted by electrolysis only, while metals below carbon can be extracted by reduction with carbon.
Tips to avoid common mistakes in Reactivity series
- ● Understand that concentration impacts reaction rate via collision frequency: more particles in the same volume, more collisions.
- ● Write the generic equation 'acid + base → salt + water' at the top of your paper as a reminder.
- ● Commit to memory that the thermal decomposition of calcium carbonate (and hydrocarbons) happens even without oxygen present.
- ● Remember that acid-base neutralisation produces water (H2O) — not hydrogen (H2).
- ● Review redox reactions and their characteristic products, particularly hydrogen gas when metals react with acids.
More topics in Unit 9 — Metals
Reactivity series sits alongside these Chemistry decks in the same syllabus unit. Each uses the same spaced-repetition system, so progress in one informs the next.
Cambridge syllabus keywords to use in your answers
These are the official Cambridge 0620 terms tagged to this section. Mark schemes credit responses that use the exact term — weave them into your answers verbatim rather than paraphrasing.
Key terms covered in this Reactivity series deck
Every term below is defined in the flashcards above. Use the list as a quick recall test before your exam — if you can't define one of these in your own words, flip back to that card.
Related Chemistry guides
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