9.2

Reactivity series

Cambridge IGCSE Chemistry (0620)  · Unit 9: Metals  · 17 flashcards

Reactivity series is topic 9.2 in the Cambridge IGCSE Chemistry (0620) syllabus , positioned in Unit 9 — Metals , alongside Properties of metals, Extraction of metals and Uses of metals.  In one line: Group 1 metals have fixed oxidation states. They consistently form +1 ions due to easily losing their one outer electron.

This topic is examined in Paper 1 (multiple-choice) and Papers 3/4 (theory), plus Paper 5 or Paper 6 (practical / alternative to practical). Past papers from 2022 to 2025 confirm this is a high-yield topic: Cambridge has set undefined questions worth 501 marks here (about 7.9% of all Chemistry marks across those years).

The deck below contains 17 flashcards — 2 definitions, 13 key concepts and 2 identification cards — covering the precise wording mark schemes reward.  Use the 2 definition cards to lock down command-word answers (define, state), then move on to the concept and application cards to handle explain, describe and compare questions.

Key definition

The oxidation states of Group 1 metals

Group 1 metals have fixed oxidation states. They consistently form +1 ions due to easily losing their one outer electron.

What the Cambridge 0620 syllabus says

Official 2026-2028 spec

These are the exact learning objectives Cambridge sets for this topic. Match the command word (Describe, Explain, State, etc.) in your answer to score full marks.

  1. Describe Describe the uses of metals in terms of their physical properties, including: (a) aluminium in the manufacture of aircraft because of its low density (b) aluminium in the manufacture of overhead electrical cables because of its low density and good electrical conductivity (c) aluminium in food containers because of its resistance to corrosion (d) copper in electrical wiring because of its good electrical conductivity and ductility
Key Concept Flip

Why is aluminium used in aircraft manufacture?

Answer Flip

Aluminium is used in aircraft due to its low density. This reduces the overall weight of the aircraft, improving fuel efficiency and performance.

Key Concept Flip

Why is aluminium used in overhead electrical cables?

Answer Flip

Aluminium is suitable for overhead cables because it possesses both low density and good electrical conductivity. Low density minimizes the load on support structures, while good conductivity ensures efficient power transmission.

Key Concept Flip

Explain why aluminium is used in food containers.

Answer Flip

Aluminium is used in food containers due to its resistance to corrosion. This prevents the aluminium from reacting with the food, preserving its quality and safety.

Key Concept Flip

Why is copper used in electrical wiring?

Answer Flip

Copper is used in electrical wiring because of its good electrical conductivity and ductility. High conductivity allows for efficient electron flow, and its ductility allows it to be drawn into wires easily.

Key Concept Flip

Do Group 1 metals show catalytic behavior?

Answer Flip

No, Group 1 metals do not exhibit catalytic behavior. Transition metals are more commonly used as catalysts.

Definition Flip

What are the oxidation states of Group 1 metals?

Answer Flip

Group 1 metals have fixed oxidation states. They consistently form +1 ions due to easily losing their one outer electron.

Key Concept Flip

Describe TWO observations you could make when potassium reacts with water.

Answer Flip

Possible observations include: the potassium moves/floats on the water's surface; it dissolves/disappears as it reacts; bubbles/effervescence/fizzing occurs; a lilac flame is produced; the potassium may explode; the potassium melts/forms a spherical shape.

Key Concept Flip

Write the balanced chemical equation for the reaction of potassium with water, including state symbols.

Answer Flip

2K(s) + 2H₂O(l) → 2KOH(aq) + H₂(g). This equation shows that potassium reacts with water to produce potassium hydroxide and hydrogen gas.

Key Concept Flip

How do the melting points of transition elements compare to those of Group 1 elements?

Answer Flip

Transition elements generally have higher melting points compared to Group 1 elements. This is due to stronger metallic bonding.

Key Concept Flip

How do the densities of transition elements compare to Group 1 elements?

Answer Flip

Transition elements generally have higher densities than Group 1 elements. This relates to the size and arrangement of their atoms.

Key Concept Flip

If chlorine is added to potassium bromide solution, what colour change is observed?

Answer Flip

The solution changes from colourless to orange/brown. This is because bromine is displaced.

Key Concept Flip

In the reaction between chlorine and potassium bromide, which element is reduced?

Answer Flip

In the reaction between chlorine and potassium bromide, bromine is displaced. Chlorine gains electrons and is reduced.

Definition Flip

State the reactivity series from most reactive to least reactive, including carbon and hydrogen.

Answer Flip

Potassium > Sodium > Calcium > Magnesium > Aluminium > Carbon > Zinc > Iron > Hydrogen > Copper > Silver > Gold

Carbon and hydrogen are included as reference points: metals above carbon can be extracted by electrolysis only, while metals below carbon can be extracted by reduction with carbon.

Key Concept Flip

What is a displacement reaction? Give an example.

Answer Flip

A displacement reaction occurs when a more reactive metal takes the place of a less reactive metal in a compound.

Example: If iron is added to copper sulfate solution:<br>Fe + CuSO₄ → FeSO₄ + Cu<br><br>Iron is more reactive than copper, so it displaces copper from the solution. You would observe the blue solution turning green/colourless and brown copper appearing on the iron.
Key Concept Flip

Describe the reactions of potassium, sodium and calcium with cold water.

Answer Flip

Potassium: reacts very vigorously, producing hydrogen which ignites with a lilac flame. Potassium moves rapidly on the water surface and may explode.

Sodium: reacts vigorously, producing hydrogen. Sodium melts into a ball and moves on the water surface. No flame usually seen.

Calcium: reacts slowly, sinking and producing a steady stream of bubbles (hydrogen). The solution turns milky due to slightly soluble calcium hydroxide.

For Group I: 2K + 2H₂O → 2KOH + H₂ (similar for Na).
For calcium: Ca + 2H₂O → Ca(OH)₂ + H₂

Key Concept Flip

How can you deduce the order of reactivity from experimental results?

Answer Flip

Compare how vigorously metals react with the same reagent (e.g., dilute acid or water):

• More reactive metals react faster, produce gas more quickly, or release more heat
• In displacement reactions, a more reactive metal will displace a less reactive one
• If metal A displaces metal B from solution, A is more reactive than B

Example: If zinc displaces iron but not magnesium, the order is: Mg > Zn > Fe
Key Concept Flip

Explain why aluminium appears unreactive despite being high in the reactivity series.

Answer Flip

Aluminium quickly forms a thin, strong layer of aluminium oxide (Al₂O₃) on its surface when exposed to air. This oxide layer is very resistant to corrosion and prevents further reaction. The aluminium underneath is actually very reactive, but the protective oxide coating makes it appear unreactive. This is why aluminium is used for drinks cans and aircraft despite being above carbon in the reactivity series.

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9.1 Properties of metals 9.3 Extraction of metals

Key Questions: Reactivity series

What are the oxidation states of Group 1 metals?

Group 1 metals have fixed oxidation states. They consistently form +1 ions due to easily losing their one outer electron.

State the reactivity series from most reactive to least reactive, including carbon and hydrogen.

Potassium > Sodium > Calcium > Magnesium > Aluminium > Carbon > Zinc > Iron > Hydrogen > Copper > Silver > Gold

Carbon and hydrogen are included as reference points: metals above carbon can be extracted by electrolysis only, while metals below carbon can be extracted by reduction with carbon.

Tips to avoid common mistakes in Reactivity series

More topics in Unit 9 — Metals

Reactivity series sits alongside these Chemistry decks in the same syllabus unit. Each uses the same spaced-repetition system, so progress in one informs the next.

Cambridge syllabus keywords to use in your answers

These are the official Cambridge 0620 terms tagged to this section. Mark schemes credit responses that use the exact term — weave them into your answers verbatim rather than paraphrasing.

reactivity series reactivity potassium sodium calcium magnesium aluminium zinc iron copper silver gold displacement reaction with water reaction with acid reaction with oxygen competition

Key terms covered in this Reactivity series deck

Every term below is defined in the flashcards above. Use the list as a quick recall test before your exam — if you can't define one of these in your own words, flip back to that card.

The oxidation states of Group 1 metals
Reactivity series from most reactive to least reactive, including carbon and hydrogen

Related Chemistry guides

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