2.1 AS Level

Relative masses of atoms and molecules

Cambridge A-Level Chemistry (9701)  · Unit 2: Atoms, molecules and stoichiometry  · 7 flashcards

Relative masses of atoms and molecules is topic 2.1 in the Cambridge A-Level Chemistry (9701) syllabus , positioned in Unit 2 — Atoms, molecules and stoichiometry , alongside The mole and the Avogadro constant and Formulas.  In one line: The unified atomic mass unit (u) is defined as one-twelfth of the mass of a carbon-12 atom. It is used as a standard unit for measuring the mass of atoms and molecules.

Marked as AS Level: examined at AS Level in Paper 1 (Multiple Choice), Paper 2 (AS Structured Questions) and Paper 3 (Advanced Practical Skills). The same content may also be assumed in Paper 4 (A Level Structured Questions).

The deck below contains 7 flashcards — 5 definitions and 2 key concepts — covering the precise wording mark schemes reward.  Use the 5 definition cards to lock down command-word answers (define, state), then move on to the concept and calculation cards to handle explain, describe, calculate and compare questions.

Key definition

The unified atomic mass unit (u)

The unified atomic mass unit (u) is defined as one-twelfth of the mass of a carbon-12 atom. It is used as a standard unit for measuring the mass of atoms and molecules.

Example: The mass of one hydrogen atom is approximately 1u.

What the Cambridge 9701 syllabus says

Official 2025-2027 spec · AS Level

These are the exact learning outcomes Cambridge sets for this topic. The candidate is expected to be able to do each of these on the relevant paper.

  1. define the unified atomic mass unit as one twelfth of the mass of a carbon-12 atom
  2. define relative atomic mass, Ar, relative isotopic mass, relative molecular mass, Mr, and relative formula mass in terms of the unified atomic mass unit 2.2 The mole and the Avogadro constant Learning outcomes

Cambridge syllabus keywords to use in your answers

These are the official Cambridge 9701 terms tagged to this section. Mark schemes credit responses that use the exact term — weave them into your answers verbatim rather than paraphrasing.

unified atomic mass unit carbon-12 atom relative atomic mass relative isotopic mass relative molecular mass relative formula mass

Tips to avoid common mistakes in Relative masses of atoms and molecules

Definition Flip

Define the unified atomic mass unit (u).

Answer Flip

The unified atomic mass unit (u) is defined as one-twelfth of the mass of a carbon-12 atom. It is used as a standard unit for measuring the mass of atoms and molecules.

Example: The mass of one hydrogen atom is approximately 1u.
Definition Flip

Define relative atomic mass (Ar).

Answer Flip

Relative atomic mass (Ar) is the weighted average mass of the naturally occurring isotopes of an element, relative to one-twelfth of the mass of a carbon-12 atom. It is a dimensionless quantity.

Example: Ar of chlorine is 35.5
Definition Flip

Define relative isotopic mass.

Answer Flip

Relative isotopic mass is the mass of an isotope relative to one-twelfth of the mass of a carbon-12 atom. It is a dimensionless quantity.

Example: The relative isotopic mass of Carbon-14 is approximately 14.
Definition Flip

Define relative molecular mass (Mr).

Answer Flip

Relative molecular mass (Mr) is the sum of the relative atomic masses of all the atoms in a molecule, relative to one-twelfth of the mass of a carbon-12 atom. It is a dimensionless quantity.

Example: Mr of H₂O = 2(1) + 16 = 18.
Definition Flip

Define relative formula mass.

Answer Flip

Relative formula mass is the sum of the relative atomic masses of all the ions in a formula unit of an ionic compound, relative to one-twelfth of the mass of a carbon-12 atom. It is a dimensionless quantity.

Example: Relative formula mass of NaCl = 23 + 35.5 = 58.5.
Key Concept Flip

Explain the relationship between relative atomic mass (Ar) and the unified atomic mass unit (u).

Answer Flip

Relative atomic mass (Ar) is a ratio. It represents how many times heavier, on average, an atom of an element is compared to 1/12th the mass of a carbon-12 atom (1 u). Therefore, it is dimensionless.

Key Concept Flip

Describe how relative atomic mass (Ar) is calculated from isotopic abundance data.

Answer Flip

Ar = Σ (isotopic mass × % abundance) / 100. Multiply the mass of each isotope by its percentage abundance, sum the results, and divide by 100 to account for the percentage. This calculates the weighted average.

More Chemistry flashcards

Browse every 9701 flashcard topic by syllabus area.

All Chemistry Flashcards
1.4 Ionisation energy 2.2 The mole and the Avogadro constant

More topics in Unit 2 — Atoms, molecules and stoichiometry

Relative masses of atoms and molecules sits alongside these A-Level Chemistry decks in the same syllabus unit. Each uses the same spaced-repetition system, so progress in one informs the next.

Key terms covered in this Relative masses of atoms and molecules deck

Every term below is defined in the flashcards above. Use the list as a quick recall test before your exam — if you can't define one of these in your own words, flip back to that card.

The unified atomic mass unit (u)
Relative atomic mass (Ar)
Relative isotopic mass
Relative molecular mass (Mr)
Relative formula mass

How to study this Relative masses of atoms and molecules deck

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